Dataset of Enabling Cyclization Strategies through Carbonyl Ylide Mediated Synthesis of Malonate Enol Ethers

Malonate enol ethers are afforded in one step by condensation of cyclic ketones with α-diazomalonates under [CpRu(CH3CN)3][BArF] catalysis. Thanks to the dual reactivity of these 2-vinyloxymalonates, a range of orthogonal cyclizations is enabled that extends remarkably the scope of annulations from carbonyl ylide intermediates.

    Organizational unit
    Laboratory of Professor Jérôme Lacour
    Type
    Dataset
    DOI
    10.26037/yareta:xt74kr35jrcgblxomojxsmnd3y
    License
    Creative Commons Attribution 4.0 International
Publication date16/03/2021
Retention date26/04/2031
accessLevelPublicAccess levelPublic
SensitivityBlue
duaNoneContract on the use of data
Contributors
  • Viñas-Lóbez, Júlia
  • Levitre, Guillaume orcid
  • de Aguirre, Adiran
  • Besnard, Céline orcid
  • Poblador Bahamonde, Amalia orcid
  • Lacour, Jérôme orcid
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