Dataset of Enabling Cyclization Strategies through Carbonyl Ylide Mediated Synthesis of Malonate Enol Ethers

Malonate enol ethers are afforded in one step by condensation of cyclic ketones with α-diazomalonates under [CpRu(CH3CN)3][BArF] catalysis. Thanks to the dual reactivity of these 2-vinyloxymalonates, a range of orthogonal cyclizations is enabled that extends remarkably the scope of annulations from carbonyl ylide intermediates.

Publication date

16/03/2021

Retention date26/04/2031

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Dataset of Organic & Biomolecular Chemistry_Aliphatic amide macrocycles

2019

Public 1.6 GB