Dataset of Triple Regioselective Functionalization of Cationic [4]Helicenes via Iridium-Catalyzed Borylation and Suzuki Cross-Coupling Reactivity

In essentially one-pot, using Ir- and subsequent Pd-catalysis, tris(arene)-functionalized cationic [4]helicenes are synthesized with full regioselectivity and enantiospecificity starting from a trivial precursor (17 examples). This poly-addition of aryl groups improves key optical properties, i.e. fluorescence quantum yields and lifetimes. ECD and CPL signatures are observed up to the far-red domain, in particular with arenes prone to aggregation, simply introduced by the late-stage functionalization procedure.

    Organizational unit
    Laboratory of Professor Jérôme Lacour
    Type
    Dataset
    DOI
    10.26037/yareta:vtd325xp6nfnzpyilnrcww2dxe
    License
    Creative Commons Attribution 4.0 International
    Keywords
    Late-stage Functionalization Ir-Catalyzed Borylation [4]Helicenes C(sp2)−H functionalization (Chir)Optical Properties
Publication date06/05/2022
Retention date03/07/2032
accessLevelPublicAccess levelPublic
SensitivityUndefined
duaNoneContract on the use of data
Contributors
  • Frédéric, Lucas orcid
  • Fabri, Bibiana orcid
  • Guénée, Laure
  • Zinna, Francesco orcid
  • Di Bari, Lorenzo orcid
  • Lacour, Jérôme orcid
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