Dataset of Malonate Enol Ether Synthesis by Additions of Diester Metal Carbenes to Ketones and Subsequent Dual Orthogonal Reactivity

Effective formation of malonate enol ethers by reaction of cyclic ketones with α diazomalonates is reported using [CpRu(CH3CN)3][BArF] as catalyst. The 2 vinyloxymalonate adducts are amenable to comprehensive and orthogonal functionalizations on either malonate and enol moieties; further synergistic reactivity opens the stage to varied annulation strategies.

Publication date

28/01/2021

Retention date29/01/2031

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Laboratory of Professor Jérôme Lacour

Multistate Aggregation-Induced Chiroptical Properties of Enantiopure Disulfide-Mediated BisPyrene Macrocycles

2022

Public 151.2 MB

Laboratory of Professor Jérôme Lacour

Regiodivergent Synthesis of Oxadiazocines via Dirhodium-Catalyzed Reactivity of Oxazolidines and alpha-Imino Carbenes

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Public 1.1 GB

Laboratory of Professor Jérôme Lacour

Dataset for 2,4,5,7-Tetranitrofluorenone Oximate for the Naked-Eye Detection of H-Bond Donors and the Chiroptical Sensing of Enantiopure Reagents

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Public 616.7 MB

Laboratory of Professor Jérôme Lacour

Dataset of Organic & Biomolecular Chemistry_Aliphatic amide macrocycles

2019

Public 1.6 GB