Dataset of Malonate Enol Ether Synthesis by Additions of Diester Metal Carbenes to Ketones and Subsequent Dual Orthogonal Reactivity

Effective formation of malonate enol ethers by reaction of cyclic ketones with α diazomalonates is reported using [CpRu(CH3CN)3][BArF] as catalyst. The 2 vinyloxymalonate adducts are amenable to comprehensive and orthogonal functionalizations on either malonate and enol moieties; further synergistic reactivity opens the stage to varied annulation strategies.

    Organizational unit
    Laboratory of Professor Jérôme Lacour
    Type
    Dataset
    DOI
    License
    Creative Commons Attribution 4.0 International
Publication date28/01/2021
Retention date26/01/2031
accessLevelPublicAccess levelPublic
SensitivityBlue
licenseContract on the use of data
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Datacite metadata

    
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    <datacite:identifier identifierType="DOI">10.26037/yareta:mfhbvp6rrnhfda7rjfzaac737u</datacite:identifier>
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            <datacite:creatorName nameType="Personal">Viñas-Lóbez, Júlia</datacite:creatorName>
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            <datacite:creatorName nameType="Personal">Levitre, Guillaume</datacite:creatorName>
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            <datacite:creatorName nameType="Personal">Lacour, Jérôme</datacite:creatorName>
            <datacite:givenName>Jérôme</datacite:givenName>
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            <datacite:affiliation>Université de Genève</datacite:affiliation>
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    <datacite:titles>
        <datacite:title>Dataset of Malonate Enol Ether Synthesis by Additions of Diester Metal Carbenes to Ketones and Subsequent Dual Orthogonal Reactivity</datacite:title>
    </datacite:titles>
    <datacite:publisher>Université de Genève, Yareta</datacite:publisher>
    <datacite:publicationYear>2021</datacite:publicationYear>
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        <datacite:date dateType="Issued">2021-01-28T00:00:00Z</datacite:date>
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        <datacite:date dateType="Created">2021-01-28T20:09:46.962Z</datacite:date>
        <datacite:date dateType="Updated">2021-01-31T09:10:58.174Z</datacite:date>
        <datacite:date dateType="Accepted">2021-01-31T09:11:02.469Z</datacite:date>
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        <datacite:description descriptionType="Abstract" xml:lang="en">Effective formation of malonate enol ethers by reaction of cyclic ketones with α diazomalonates is reported using [CpRu(CH3CN)3][BArF] as catalyst. The 2 vinyloxymalonate adducts are amenable to comprehensive and orthogonal functionalizations on either malonate and enol moieties; further synergistic reactivity opens the stage to varied annulation strategies.</datacite:description>
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Packages information

    Metadata version
    2.1
    Disposal approval
    Yes
    Retention expiration
    26/01/2031 00:00:00
    Created
    31/01/2021 09:11:03
    Deposit
    Dataset of Malonate Enol Ether Synthesis by Additions of Diester Metal Carbenes to Ketones and Subsequent Dual Orthogonal Reactivity
    Deposit creation
    28/01/2021 20:09:46
    Deposit approval
    31/01/2021 09:10:58
    SIP
    Dataset of Malonate Enol Ether Synthesis by Additions of Diester Metal Carbenes to Ketones and Subsequent Dual Orthogonal Reactivity
    AIP
    Dataset of Malonate Enol Ether Synthesis by Additions of Diester Metal Carbenes to Ketones and Subsequent Dual Orthogonal Reactivity
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    Agent 4
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