Dataset of Malonate Enol Ether Synthesis by Additions of Diester Metal Carbenes to Ketones and Subsequent Dual Orthogonal Reactivity
Effective formation of malonate enol ethers by reaction of cyclic ketones with α diazomalonates is reported using [CpRu(CH3CN)3][BArF] as catalyst. The 2 vinyloxymalonate adducts are amenable to comprehensive and orthogonal functionalizations on either malonate and enol moieties; further synergistic reactivity opens the stage to varied annulation strategies.
- Organizational unit
- Laboratory of Professor Jérôme Lacour
- Type
- Dataset
- DOI
- License
- Creative Commons Attribution 4.0 International
License
Contributors
- Viñas-Lóbez, Júlia
- Levitre, Guillaume
- de Aguirre, Adiran
- Besnard, Céline
- Poblador Bahamonde, Amalia
- Lacour, Jérôme
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Datacite metadata
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<datacite:creatorName nameType="Personal">Lacour, Jérôme</datacite:creatorName>
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<datacite:affiliation>Université de Genève</datacite:affiliation>
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<datacite:titles>
<datacite:title>Dataset of Malonate Enol Ether Synthesis by Additions of Diester Metal Carbenes to Ketones and Subsequent Dual Orthogonal Reactivity</datacite:title>
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<datacite:publisher>Université de Genève, Yareta</datacite:publisher>
<datacite:publicationYear>2021</datacite:publicationYear>
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<datacite:date dateType="Issued">2021-01-28T00:00:00Z</datacite:date>
<datacite:date dateType="Collected">2021-01-28T00:00:00Z/</datacite:date>
<datacite:date dateType="Created">2021-01-28T20:09:46.962Z</datacite:date>
<datacite:date dateType="Updated">2021-01-31T09:10:58.174Z</datacite:date>
<datacite:date dateType="Accepted">2021-01-31T09:11:02.469Z</datacite:date>
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<datacite:description descriptionType="Abstract" xml:lang="en">Effective formation of malonate enol ethers by reaction of cyclic ketones with α diazomalonates is reported using [CpRu(CH3CN)3][BArF] as catalyst. The 2 vinyloxymalonate adducts are amenable to comprehensive and orthogonal functionalizations on either malonate and enol moieties; further synergistic reactivity opens the stage to varied annulation strategies.</datacite:description>
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Packages information
- Metadata version
- 2.1
- Disposal approval
- Yes
- Retention expiration
- 26/01/2031 00:00:00
- Created
- 31/01/2021 09:11:03
- Deposit
- Dataset of Malonate Enol Ether Synthesis by Additions of Diester Metal Carbenes to Ketones and Subsequent Dual Orthogonal Reactivity
- Deposit creation
- 28/01/2021 20:09:46
- Deposit approval
- 31/01/2021 09:10:58
- SIP
- Dataset of Malonate Enol Ether Synthesis by Additions of Diester Metal Carbenes to Ketones and Subsequent Dual Orthogonal Reactivity
- AIP
- Dataset of Malonate Enol Ether Synthesis by Additions of Diester Metal Carbenes to Ketones and Subsequent Dual Orthogonal Reactivity
- Agent 1
- Linux | amd64 | 4.19.0-13-amd64
- Agent 2
- AdoptOpenJDK | Software | 1.8.0_275
- Agent 3
- DLCM | Software | 2.0.9
- Agent 4
- FITS | Software | 1.5.0
- Agent 5
- ClamAV | Software | 0.102.4
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