Dataset of Malonate Enol Ether Synthesis by Additions of Diester Metal Carbenes to Ketones and Subsequent Dual Orthogonal Reactivity

Effective formation of malonate enol ethers by reaction of cyclic ketones with α diazomalonates is reported using [CpRu(CH3CN)3][BArF] as catalyst. The 2 vinyloxymalonate adducts are amenable to comprehensive and orthogonal functionalizations on either malonate and enol moieties; further synergistic reactivity opens the stage to varied annulation strategies.

    Organizational unit
    Laboratory of Professor Jérôme Lacour
    Type
    Dataset
    DOI
    10.26037/yareta:mfhbvp6rrnhfda7rjfzaac737u
    License
    Creative Commons Attribution 4.0 International
Publication date28/01/2021
Retention date29/01/2031
accessLevelPublicAccess levelPublic
SensitivityBlue
duaNoneContract on the use of data
Contributors
  • Viñas-Lóbez, Júlia
  • Levitre, Guillaume orcid
  • de Aguirre, Adiran
  • Besnard, Céline orcid
  • Poblador Bahamonde, Amalia orcid
  • Lacour, Jérôme orcid
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