• Home
en
  1. Home
  2. Dataset of Access to Chiral Rigid Hemicyanine Fluorophores from Tröger Bases and alpha-Imino Carbenes

Dataset of Access to Chiral Rigid Hemicyanine Fluorophores from Tröger Bases and alpha-Imino Carbenes

Chiral hemicyanine fluorophores are afforded in three steps only from Tröger bases via α-imino carbene additions, an original aminal deprotection and Cu(II)-mediated oxidations. The stable benzodiazepinoindolium salts are readily isolated and present (chir)optical properties that can be fine-tuned by late-stage cross-coupling functionalization. The hemicyanine character of dyes was rationalized using first principles.

    Organizational unit
    Laboratory of Professor Jérôme Lacour
    Type
    Dataset
    DOI
    10.26037/yareta:eazlum7ynbbvvn4sdrv7qkopqe
    License
    Creative Commons Attribution 4.0 International
Publication date13/08/2020
Retention date08/09/2030
accessLevelPublicAccess levelPublic
SensitivityUndefined
duaNoneContract on the use of data
Contributors
  • Saleh, Nidal orcid
  • Bosmani, Alessandro
  • Besnard, Céline orcid
  • Bürgi, Thomas orcid
  • Jacquemin, Denis orcid
  • Lacour, Jérôme orcid
10
0
  • Quality (0 Reviews)
  • Usefulness (0 Reviews)

Datacite metadata

Packages information

Similar archives

Laboratory of Professor Jérôme Lacour
Dataset of Organic & Biomolecular Chemistry_Aliphatic amide macrocycles
2019 accessLevelPublic Public 1.6 GB
Laboratory of Professor Jérôme Lacour
Dataset of submission_Photo-Induced Thiol-Ene Reactions of Unsaturated Polyether Macrocycles
2019 accessLevelPublic Public 1016.2 MB
Laboratory of Professor Jérôme Lacour
Dataset of Preparation and structural characterization of [CpRu(1,10-phenanthroline)(CH3CN)][X] and precursor complexes (X= PF6, BArF, TRISPHAT-N)
2020 accessLevelPublic Public 350.4 MB
Laboratory of Professor Jérôme Lacour
Dataset of Merging polyacenes and cationic helicenes
2019 accessLevelPublic Public 1.0 GB
All rights reserved by DLCM and the University of GenevaunigeBlack