Dataset for Concave P-Stereogenic Phosphorodiamidite Ligands for Enantioselective Rh(I)-Catalysis

The development of a new class of concave P-stereogenic phosphorodiamidite ligands, derived from Tröger Bases (TBs), is explored. These ligands, characterized by their remarkable stability and unique structural geometry around the P-atom, are used in asymmetric Rh(I)-catalyzed additions of boronic acids to NH-isatins resulting in excellent reactivities and reasonable enantioselectivity (e.r. up to 92:8).

    Organizational unit
    Laboratory of Professor Jérôme Lacour
    Type
    Dataset
    DOI
    10.26037/yareta:c2rz2xbxancklnkqgvqkqbxl3a
    License
    Creative Commons Attribution 4.0 International
Publication date29/01/2024
Retention date26/01/2034
accessLevelPublicAccess levelPublic
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licenseContract on the use of data
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Contributors
  • Saleh, Nidal orcid
  • Besnard, Céline orcid
  • Lacour, Jérôme orcid
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