Dataset for Concave P-Stereogenic Phosphorodiamidite Ligands for Enantioselective Rh(I)-Catalysis

The development of a new class of concave P-stereogenic phosphorodiamidite ligands, derived from Tröger Bases (TBs), is explored. These ligands, characterized by their remarkable stability and unique structural geometry around the P-atom, are used in asymmetric Rh(I)-catalyzed additions of boronic acids to NH-isatins resulting in excellent reactivities and reasonable enantioselectivity (e.r. up to 92:8).

    Organizational unit
    Laboratory of Professor Jérôme Lacour
    Creative Commons Attribution 4.0 International
Publication date29/01/2024
Retention date26/01/2034
accessLevelPublicAccess levelPublic
licenseContract on the use of data
  • Saleh, Nidal orcid
  • Besnard, Céline orcid
  • Lacour, Jérôme orcid
  • Quality (0 Reviews)
  • Usefulness (0 Reviews)

Datacite metadata

Packages information

Similar archives

Laboratory of Professor Jérôme Lacour
Dataset of Organic & Biomolecular Chemistry_Aliphatic amide macrocycles
2019 accessLevelPublic Public 1.6 GB
Laboratory of Professor Jérôme Lacour
Dataset of submission_Photo-Induced Thiol-Ene Reactions of Unsaturated Polyether Macrocycles
2019 accessLevelPublic Public 1016.2 MB
Laboratory of Professor Jérôme Lacour
Multistate Aggregation-Induced Chiroptical Properties of Enantiopure Disulfide-Mediated BisPyrene Macrocycles
2022 accessLevelPublic Public 151.2 MB
Laboratory of Professor Jérôme Lacour
Regiodivergent Synthesis of Oxadiazocines via Dirhodium-Catalyzed Reactivity of Oxazolidines and alpha-Imino Carbenes
2023 accessLevelPublic Public 1.1 GB
All rights reserved by DLCM and the University of GenevaunigeBlack