Dataset of Circularly polarized luminescence from Tb(III) interacting with chiral polyether macrocycles

A straightforward two-step synthesis protocol affords a series of chiral amide-based bis-pyridine substituted polyether macrocycles. One ligand is particularly able to complex Terbium(III) ion spontaneously. Upon complexation, interesting chiroptical properties are observed both in absorbance (ECD) and in fluorescence (CPL). In ligand-centered electronic circular dichroism, a sign inversion coupled with a signal enhancement is measured; while an easily detectable metal-centered circularly polarized luminescence with a glum of 0.05 is obtained for the main 5D4 → 7F5 terbium transition. The coordination mode and structure of the complex was studied using different analysis methods (NMR analysis, spectrophotometric titration and solid-state elucidation)

    Organizational unit
    Laboratory of Professor Jérôme Lacour
    Type
    Dataset
    DOI
    10.26037/yareta:rj5oxgsdxrhqdm7g6p6gnu4iiy
    License
    Creative Commons Attribution 4.0 International
Publication date10/08/2020
Retention date04/10/2032
accessLevelPublicAccess levelPublic
SensitivityUndefined
duaNoneContract on the use of data
Contributors
  • Homberg, Alexandre orcid
  • Navazio, Federica
  • Le Tellier, Antoine
  • Zinna, Francesco orcid
  • Fürstenberg, Alexandre orcid
  • Besnard, Céline orcid
  • Di Bari, Lorenzo orcid
  • Lacour, Jérôme orcid
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