Dataset for General Ir-Catalyzed N-H Insertions of Diazomalonates into Aliphatic and Aromatic Amines

A general N-H insertion reactivity of acceptor-acceptor diazo malonate reagents is reported using [Ir(cod)Cl]2 as catalyst. A large range of amines, primary and secondary, aliphatic and aromatic, is possible. Mild temperatures, perfect substrate / reactant stoichiometry, and good functional group compatibility render the process particularly attractive for the (late-stage) functionalization of amines.

    Organizational unit
    Laboratory of Professor Jérôme Lacour
    Type
    Dataset
    DOI
    10.26037/yareta:blwwovyd75g5vox7g7i42zvnhm
    License
    Creative Commons Attribution 4.0 International
Publication date02/10/2023
Retention date29/09/2033
accessLevelPublicAccess levelPublic
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licenseContract on the use of data
License
Contributors
  • Zhong, Zhuang
  • Besnard, Céline orcid
  • Lacour, Jérôme orcid
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