Dataset for Selective Synthesis of Tetrahydro Oxepines by Cu-Catalyzed Condensations of Diazomalonates and gem-Dialkyl Vinyl Oxetanes

Thanks to an unprecedented gem-dialkyl substituent effect, an efficient synthesis of tetrahydro oxepine derivatives is achieved by ring expansion of vinyl oxetanes using acceptor (acceptor) diazo reagents under Cu(II)-catalysis. A large scope of 2-vinyl oxetanes and either diazo mono or diester reagents give access to a series of functionalized oxepines

Organizational unit: Laboratory of Professor Jérôme Lacour

Type: Dataset

DOI: 10.26037/yareta:avvk7mhotjdd7i3acozd6v5274

License: Creative Commons Attribution 4.0 International

Publication date

27/11/2023

Retention date24/11/2033

Access levelPublic

SensitivityBlue

Contract on the use of data

License

Contributors

Montagnon, Claire

Pertschi, Romain

Besnard, Céline

Lacour, Jérôme

Files

17173 Files (3.7 GB)

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