Dataset for Selective Synthesis of Tetrahydro Oxepines by Cu-Catalyzed Condensations of Diazomalonates and gem-Dialkyl Vinyl Oxetanes

Thanks to an unprecedented gem-dialkyl substituent effect, an efficient synthesis of tetrahydro oxepine derivatives is achieved by ring expansion of vinyl oxetanes using acceptor (acceptor) diazo reagents under Cu(II)-catalysis. A large scope of 2-vinyl oxetanes and either diazo mono or diester reagents give access to a series of functionalized oxepines

    Organizational unit
    Laboratory of Professor Jérôme Lacour
    Type
    Dataset
    DOI
    10.26037/yareta:avvk7mhotjdd7i3acozd6v5274
    License
    Creative Commons Attribution 4.0 International
Publication date27/11/2023
Retention date24/11/2033
accessLevelPublicAccess levelPublic
SensitivityBlue
licenseContract on the use of data
License
Contributors
  • Montagnon, Claire
  • Pertschi, Romain orcid
  • Besnard, Céline orcid
  • Lacour, Jérôme orcid
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