Dataset for Synthesis and Properties of Chiral Fluorescent Helicene-BODIPY Conjugates

A series of chiral fluorescent helicene-BODIPY conjugates was prepared by the regioselective formylation of aza[4]helicene precursors and then an efficient one-pot two-step BODIPY synthesis (13 examples, 28-82%). Fused conjugates exhibit absorption and fluorescence properties (ΦF 30-45%) in the red visible domain, and a CPL signature could be measured at 605 nm (glum ±5·10-4). Photophysical and electronic properties were investigated and rationalized through first principles

Organizational unit: Laboratory of Professor Jérôme Lacour

Type: Dataset

DOI: 10.26037/yareta:qs3vif5ggbc6jpanuricxbkrbm

License: Creative Commons Attribution 4.0 International

Publication date

27/08/2020

Retention date25/08/2030

Access levelPublic

SensitivityUndefined

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Contributors

Moneva Lorente, Pau

Wallabregue, Antoine

Di Bari, Lorenzo

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        <datacite:title>Dataset for Synthesis and Properties of Chiral Fluorescent Helicene-BODIPY Conjugates</datacite:title>
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        <datacite:description descriptionType="Abstract" xml:lang="en">A series of chiral fluorescent helicene-BODIPY conjugates was prepared by the regioselective formylation of aza[4]helicene precursors and then an efficient one-pot two-step BODIPY synthesis (13 examples, 28-82%). Fused conjugates exhibit absorption and fluorescence properties (ΦF 30-45%) in the red visible domain, and a CPL signature could be measured at 605 nm (glum ±5·10-4). Photophysical and electronic properties were investigated and rationalized through first principles</datacite:description>
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