Dataset for Synthesis and Properties of Chiral Fluorescent Helicene-BODIPY Conjugates

A series of chiral fluorescent helicene-BODIPY conjugates was prepared by the regioselective formylation of aza[4]helicene precursors and then an efficient one-pot two-step BODIPY synthesis (13 examples, 28-82%). Fused conjugates exhibit absorption and fluorescence properties (ΦF 30-45%) in the red visible domain, and a CPL signature could be measured at 605 nm (glum ±5·10-4). Photophysical and electronic properties were investigated and rationalized through first principles

Publication date

27/08/2020

Retention date09/09/2030

Access levelPublic

SensitivityUndefined

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Dataset of Organic & Biomolecular Chemistry_Aliphatic amide macrocycles

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Public 1.6 GB